All 1:63360 series and the early 1:50000 maps were all engraved on glass. These were the original master maps. They were not exactly carved in glass but where etched. Glass is very stable, more so than copper or zink. These glass maps were made by coating the glass with wax and then scribing the information in the the wax. From this the plates are photographed to make the zinc printing plates. The glass is then acid etched to be kept in the archive . My dear friend and OS glass engraver Clive Norris worked for OS until the late 70's.
When I needed historical mapping for a customer I would ring the archive and one of the to old gentlemen that worked there would go and find the corresponding map within the date range that was required and a couple of days later I would receive a paper copy of the map. This archive has been completely digitised now and the complete contents of the archive has been transferred to English Heritage. I worked on scanning a very small percentage of the archive.
I have just come across this video from 1953 which shows an over view of map making by OS. I have sent a link of it to Clive to see if he features in it.